Regulation of anodic potential oscillation in manganese metal electrolysis by hyperchaotic current

XIE Zi-nan; LIU Zuo-hua; LI Chun-biao; ZHANG Xin; GU Jia-cheng; LI Qiang; TAO Chang-yuan

doi:10.13374/j.issn2095-9389.2020.12.01.002

Volume 43 Issue 8

Aug. 2021

Turn off MathJax

Article Contents

Article Navigation > Chinese Journal of Engineering > 2021 > 43(8): 1047-1054

XIE Zi-nan, LIU Zuo-hua, LI Chun-biao, ZHANG Xin, GU Jia-cheng, LI Qiang, TAO Chang-yuan. Regulation of anodic potential oscillation in manganese metal electrolysis by hyperchaotic current[J]. Chinese Journal of Engineering, 2021, 43(8): 1047-1054. doi: 10.13374/j.issn2095-9389.2020.12.01.002

Citation:

XIE Zi-nan, LIU Zuo-hua, LI Chun-biao, ZHANG Xin, GU Jia-cheng, LI Qiang, TAO Chang-yuan. Regulation of anodic potential oscillation in manganese metal electrolysis by hyperchaotic current[J]. Chinese Journal of Engineering, 2021, 43(8): 1047-1054. doi: 10.13374/j.issn2095-9389.2020.12.01.002

Citation:

XIE Zi-nan, LIU Zuo-hua, LI Chun-biao, ZHANG Xin, GU Jia-cheng, LI Qiang, TAO Chang-yuan. Regulation of anodic potential oscillation in manganese metal electrolysis by hyperchaotic current[J]. Chinese Journal of Engineering, 2021, 43(8): 1047-1054. doi: 10.13374/j.issn2095-9389.2020.12.01.002

PDF( 1324 KB)

Regulation of anodic potential oscillation in manganese metal electrolysis by hyperchaotic current

doi: 10.13374/j.issn2095-9389.2020.12.01.002

1.
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
2.
School of Materials and Chemical Engineering, Tongren University, Tongren 554300, China
3.
School of Electronics and Information Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, China

More Information

Corresponding author: E-mail: liuzuohua@cqu.edu.cn
Received Date: 2020-12-01
Available Online: 2021-07-22
Publish Date: 2021-08-25

Abstract

Abstract

Manganese metal electrolysis is a typical nonlinear system far from the equilibrium state. In this case, nonlinear behaviors such as electrochemical oscillation and metal fractal occur in the electrode reaction process. The multiple valence state changes of manganese and the nonlinear coupling of multiple chemical reactions cause the electrolytic process to be unstable and unmanageable, and increase extra energy consumption. Therefore, a study regarding the physical and chemical processes of the electrode/solution interface will help in revealing the electrode reaction mechanism and elaborate the nonlinear behaviors of the interface reaction process. This should control the electrode reaction process more effectively and regulate the entire process more efficiently. This paper presents a new mode of chaotic current electrolysis by introducing a hyperchaotic circuit instead of the original direct current power supply. Galvanostatic polarization, anode polarization, the Tafel test, X-ray diffraction, and scanning electron microscopy were employed to analyze the relationship between the electrochemical oscillation behavior and anodic deposited manganese oxides on lead alloy anodes. Research results show that the potential oscillation behavior of the anode is suppressed to a certain extent. The average oscillation period was increased by 5.6 s, and the average oscillation amplitude was reduced by 38 mV compared with direct current polarization after 350 A·m^?2 constant current polarization for 30 min. This would help to reduce the generation of anode slime and additional energy consumption during electrolysis. At the same time, the deposited MnO₂ on the anode under hyperchaotic current had a dense and flat surface, which improved the oxygen evolution reaction activity and the corrosion resistance of the lead alloy anode. The comprehensive analysis demonstrated that the application of hyperchaotic current to manganese metal electrolysis could achieve effective regulation of anode electrochemical oscillation, providing a new insight for the further reduction in the energy consumption and pollution emission in the electrolysis process.
- electrolytic manganese metal,
- electrochemical oscillation,
- chaotic circuit,
- hyperchaotic current,
- energy conservation and emission reduction

FullText(HTML)

References(27)

References

[1]	譚柱中, 張麗云. 中國電解金屬錳工業研究進展. 中國錳業, 2019, 37(2):1 Tan Z Z, Zhang L Y. A research progress in electrolytic manganese metal industry of China. China’s Manganese Ind, 2019, 37(2): 1
[2]	呂東亞, 馬保中, 陳永強, 等. 鹽酸法富集低品位錳礦及酸介質高值再生工藝. 工程科學學報, 2020, 42(5):578 Lü D Y, Ma B Z, Chen Y Q, et al. Beneficiation of low-grade manganese ore by hydrochloric acid leaching and high-value regeneration of acid medium. Chin J Eng, 2020, 42(5): 578
[3]	張小軍, 黃惠, 董勁, 等. 鋅電積過程中錳元素對鋁陰極的電化學行為影響. 工程科學學報, 2018, 40(7):800 Zhang X J, Huang H, Dong J, et al. Influence of manganese on the electrochemical behavior of an aluminum cathode used in zinc electrowinning. Chin J Eng, 2018, 40(7): 800
[4]	Zhang R R, Ma X T, Shen X X, et al. Life cycle assessment of electrolytic manganese metal production. J Clean Prod, 2020, 253: 119951 doi: 10.1016/j.jclepro.2019.119951
[5]	Fernández-Barcia M, Hoffmann V, Oswald S, et al. Electrodeposition of manganese layers from sustainable sulfate based electrolytes. Surf Coat Technol, 2018, 334: 261 doi: 10.1016/j.surfcoat.2017.11.028
[6]	牛穎超, 那春光, 吳尚昆. 礦產資源保障能力評價與分析——以錳礦為例. 中國國土資源經濟, 2021, 34(4):78 Niu Y C, Na C G, Wu S K. Evaluation and analysis of mineral resource security capability —a case study of manganese ore. Nat Resour Econ China, 2021, 34(4): 78
[7]	Yang F, Jiang L X, Yu X Y, et al. Catalytic effects of $ {\rm{N}}_4^+ $ on hydrogen evolution and manganese electrodeposition on stainless steel. Trans Nonferrous Met Soc China, 2019, 29(11): 2430 doi: 10.1016/S1003-6326(19)65149-6
[8]	陶長元, 劉作華, 范興. 電解錳節能減排理論與工程應用. 重慶: 重慶大學出版社, 2018 Tao C Y, Liu Z H, Fan X. The Theory and Engineering Application of Electrolytic Manganese Energy Saving and Emission Reduction. Chongqing: Chongqing University Press, 2018
[9]	Forghani M, McCarthy J, Donne S W. Oscillatory current behavior in energy storage electrode materials. J Electrochem Soc, 2019, 166(15): A3620 doi: 10.1149/2.0701915jes
[10]	Yang Y X, Zhou H, Zhang Q, et al. Template-free electrodeposition of dendritic metal blades for efficient flexible manganese oxide electrode. J Electrochem Soc, 2019, 166(15): A3559 doi: 10.1149/2.0181915jes
[11]	Fan X, Hou J, Sun D G, et al. Mn-oxides catalyzed periodic current oscillation on the anode. Electrochimica Acta, 2013, 102: 466 doi: 10.1016/j.electacta.2013.03.175
[12]	Fan X, Yang D, Ding L, et al. Periodic current oscillation catalyzed by δ-MnO₂ nanosheets. Chemphyschem, 2015, 16(1): 176 doi: 10.1002/cphc.201402623
[13]	Bai H, Qing S L, Yang D P, et al. Periodic potential oscillation during oxygen evolution catalyzed by manganese oxide at constant current. J Electrochem Soc, 2017, 164(4): E78 doi: 10.1149/2.1241704jes
[14]	Xie Z N, Liu Z H, Zhang X J, et al. Electrochemical oscillation on anode regulated by sodium oleate in electrolytic metal manganese. J Electroanal Chem, 2019, 845: 13 doi: 10.1016/j.jelechem.2019.05.012
[15]	Zhou H, Zhang N N, Bai H, et al. A pulse modulatable self-oscillation kinetics for water oxidation at large current on manganese catalyst. Electrochimica Acta, 2020, 337: 135798 doi: 10.1016/j.electacta.2020.135798
[16]	Xie Z N, Liu Z H, Chang J, et al. Electrochemical behaviors of MnO₂ on lead alloy anode during pulse electrodeposition for efficient manganese electrowinning. ACS Sustain Chem Eng, 2020, 8(39): 15044 doi: 10.1021/acssuschemeng.0c06259
[17]	Bao B C, Bao H, Wang N, et al. Hidden extreme multistability in memristive hyperchaotic system. Chaos Solitons Fractals, 2017, 94: 102 doi: 10.1016/j.chaos.2016.11.016
[18]	Kumar S, Strachan J P, Stanley Williams R. Chaotic dynamics in nanoscale NbO₂ Mott memristors for analogue computing. Nature, 2017, 548(7667): 318 doi: 10.1038/nature23307
[19]	Jiang X, Shao L, Zhang S X, et al. Chaos-assisted broadband momentum transformation in optical microresonators. Science, 2017, 358(6361): 344 doi: 10.1126/science.aao0763
[20]	Chai X L, Fu X L, Gan Z H, et al. A color image cryptosystem based on dynamic DNA encryption and chaos. Signal Process, 2019, 155: 44 doi: 10.1016/j.sigpro.2018.09.029
[21]	Bao B C, Jiang T, Wang G Y, et al. Two-memristor-based Chua's hyperchaotic circuit with plane equilibrium and its extreme multistability. Nonlinear Dyn, 2017, 89(2): 1157 doi: 10.1007/s11071-017-3507-0
[22]	Hu X K, Zhou P. Circuit realization of a 3D multistability chaotic system and its synchronization via linear resistor and linear capacitor in parallel coupling. Complexity, 2020, 2020: 9846934
[23]	Li C B, Sprott J C. An infinite 3-D quasiperiodic lattice of chaotic attractors. Phys Lett A, 2018, 382(8): 581 doi: 10.1016/j.physleta.2017.12.022
[24]	Li C B, Sun J Y, Lu T, et al. Polarity balance for attractor self-reproducing. Chaos, 2020, 30(6): 063144 doi: 10.1063/5.0007668
[25]	Jaimes R, Miranda-Hernández M, Lartundo-Rojas L, et al. Characterization of anodic deposits formed on Pb-Ag electrodes during electrolysis in mimic zinc electrowinning solutions with different concentrations of Mn(II). Hydrometallurgy, 2015, 156: 53 doi: 10.1016/j.hydromet.2015.05.008
[26]	Zhang C M, Duan N, Jiang L H, et al. The impact mechanism of Mn²⁺ ions on oxygen evolution reaction in zinc sulfate electrolyte. J Electroanal Chem, 2018, 811: 53 doi: 10.1016/j.jelechem.2018.01.040
[27]	Schmachtel S, Murtom?ki L, Aromaa J, et al. Simulation of electrochemical processes during oxygen evolution on Pb-MnO₂ composite electrodes. Electrochimica Acta, 2017, 245: 512 doi: 10.1016/j.electacta.2017.04.131