Thermal cycling stability of Ni55Mn25Ga18Ti2 high-temperature shape memory alloy

XIN Yan; WANG Fu-xing

doi:10.13374/j.issn2095-9389.2021.02.26.001

Volume 44 Issue 6

May 2022

Turn off MathJax

Article Contents

Article Navigation > Chinese Journal of Engineering > 2022 > 44(6): 1020-1026

XIN Yan, WANG Fu-xing. Thermal cycling stability of Ni55Mn25Ga18Ti2 high-temperature shape memory alloy[J]. Chinese Journal of Engineering, 2022, 44(6): 1020-1026. doi: 10.13374/j.issn2095-9389.2021.02.26.001

Citation:

XIN Yan, WANG Fu-xing. Thermal cycling stability of Ni₅₅Mn₂₅Ga₁₈Ti₂ high-temperature shape memory alloy[J]. Chinese Journal of Engineering, 2022, 44(6): 1020-1026. doi: 10.13374/j.issn2095-9389.2021.02.26.001

Citation:

PDF( 1155 KB)

Thermal cycling stability of Ni₅₅Mn₂₅Ga₁₈Ti₂ high-temperature shape memory alloy

doi: 10.13374/j.issn2095-9389.2021.02.26.001

XIN Yan^,,
WANG Fu-xing

School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing 102206, China

More Information

Corresponding author: E-mail: xinyan@ncepu.edu.cn
Received Date: 2021-02-26
Available Online: 2021-04-07
Publish Date: 2022-06-25

Abstract

Abstract

Research on high-temperature shape memory alloys has attracted much attention due to the control requirements of the high-temperature drive (>100 ℃) and the overheating warning in high voltage transmissions, nuclear power, aerospace, automotive, oil exploration, and other engineering fields. High-temperature shape memory alloys refer to those with reverse martensitic transformation starting temperature (A_s) higher than 100 ℃. A wide range of high-temperature shape memory alloys exists, including Ti?Ni?Pd/Pt, Ni?Ti?Hf/Zr, Cu?Al?Ni, Ni?Mn?Ga, Ru-based, β-Ti-based, and Co-based systems. Besides the high transformation temperatures and good mechanical and shape memory properties, the thermal stability of microstructures and properties at high temperatures and after thermal cycling transformations is also an important basis for evaluating the practicability of high-temperature shape memory alloys. Dual-phase Ni?Mn?Ga?Ti high-temperature shape memory alloys were chosen because of their better ductility compared with single-phase Ni?Mn?Ga alloys. In this paper, the as-quenched Ni₅₅Mn₂₅Ga₁₈Ti₂ high-temperature shape memory alloy was prepared. Specimens are then thermal-cycled at a temperature between the room temperature and 480 ℃ for 5, 10, 50, 100, and 500 times. The thermal stability of the microstructure, martensitic transformation temperatures, and mechanical and shape memory properties were studied by X-ray diffraction analysis, scanning electron microscopy, simultaneous thermal analyzer, and room-temperature compression analysis. Results show that there are no obvious changes in the phase structure and microstructure of the Ni₅₅Mn₂₅Ga₁₈Ti₂ high-temperature shape memory alloy after 500 thermal cycles. All as-quenched and thermal-cycled specimens show dual-phase structures with non-modulated tetragonal martensite and Ni-rich face-centered-cubic γ phase. With the increase of thermal cycling times, the forward martensitic transformation temperatures are almost kept constant, and the reverse martensitic transformation temperatures and the hysteresis are observed to be steady when the thermal cycles exceed five times. After 500 thermal cycles, the compressive strength and compressive stain slightly change, and the shape memory strain drops but remains over 1.4%. The Ni₅₅Mn₂₅Ga₁₈Ti₂ high-temperature shape memory alloy shows high thermal cycling stability.
- Ni?Mn?Ga?Ti,
- high-temperature shape memory alloy,
- thermal cycling stability,
- microstructure,
- martensitic transformation

FullText(HTML)

References(38)

References

[1]	Mohd Jani J, Leary M, Subic A, et al. A review of shape memory alloy research, applications and opportunities. Mater Des, 2014, 56: 1078 doi: 10.1016/j.matdes.2013.11.084
[2]	賀志榮, 周超, 劉琳, 等. 形狀記憶合金及其應用研究進展. 鑄造技術, 2017, 38(2):257 He Z R, Zhou C, Liu L, et al. Research progress of shape memory alloys and their applications. Foundry Technol, 2017, 38(2): 257
[3]	Ma J, Karaman I, Noebe R D. High temperature shape memory alloys. Int Mater Rev, 2010, 55(5): 257 doi: 10.1179/095066010X12646898728363
[4]	左舜貴, 金學軍, 金明江. 高溫形狀記憶合金的研究進展. 機械工程材料, 2014, 38(1):1 Zuo S G, Jin X J, Jin M J. Research progress in high temperature shape memory alloys. Mater Mech Eng, 2014, 38(1): 1
[5]	Van Humbeeck J. Shape memory alloys with high transformation temperatures. Mater Res Bull, 2012, 47(10): 2966 doi: 10.1016/j.materresbull.2012.04.118
[6]	Rehman S U, Khan M, Khan A N, et al. Quaternary alloying of copper with Ti₅₀Ni₂₅Pd₂₅ high temperature shape memory alloys. Mater Sci Eng A, 2019, 763: 138148 doi: 10.1016/j.msea.2019.138148
[7]	蔡偉, 孟祥龍, 趙新青, 等. TiNi基高溫形狀記憶合金的馬氏體相變與形狀記憶效應. 中國材料進展, 2012, 31(12):40 Cai W, Meng X L, Zhao X Q, et al. Martensitic transformation and shape memory effect of Ti?Ni based high temperature shape memory alloys. Mater China, 2012, 31(12): 40
[8]	Tong Y X, Fan X M, Shuitcev A V, et al. Effects of Sc addition and aging on microstructure and martensitic transformation of Ni-rich NiTiHfSc high temperature shape memory alloys. J Alloys Compd, 2020, 845: 156331 doi: 10.1016/j.jallcom.2020.156331
[9]	馮昭偉, 崔躍, 尚再艷, 等. 鎳鈦鋯高溫形狀記憶合金的研究進展. 材料導報, 2016, 30(增刊2): 616 Feng Z W, Cui Y, Shang Z Y, et al. Development of NiTiZr high temperature shape memory alloys. Mater Rev, 2016, 30(Sup 2): 616
[10]	López-Ferre?o I, Gómez-Cortés J F, Breczewski T, et al. High-temperature shape memory alloys based on the Cu?Al?Ni system: Design and thermomechanical characterization. J Mater Res Technol, 2020, 9(5): 9972 doi: 10.1016/j.jmrt.2020.07.002
[11]	Xu H B, Li Y, Jiang C B. Ni?Mn?Ga high-temperature shape memory alloys. Mater Sci Eng A, 2006, 438-440: 1065 doi: 10.1016/j.msea.2006.02.187
[12]	Pérez-Checa A, Feuchtwanger J, Barandiaran J M, et al. Ni?Mn?Ga high temperature shape memory alloys: Function stability in β and β+γ regions. J Alloys Compd, 2018, 741: 148 doi: 10.1016/j.jallcom.2018.01.068
[13]	Manzoni A M, Denquin A, Vermaut P, et al. Constrained hierarchical twinning in Ru-based high temperature shape memory alloys. Acta Mater, 2016, 111: 283 doi: 10.1016/j.actamat.2016.03.067
[14]	李啟泉, 李巖, 馬悅輝. 鈦基高溫形狀記憶合金進展綜述. 材料導報, 2020, 34(3):148 Li Q Q, Li Y, Ma Y H. Research progress of titanium-based high-temperature shape memory alloy. Mater Rep, 2020, 34(3): 148
[15]	Buenconsejo P J S, Kim H Y, Hosoda H, et al. Shape memory behavior of Ti–Ta and its potential as a high-temperature shape memory alloy. Acta Mater, 2009, 57(4): 1068 doi: 10.1016/j.actamat.2008.10.041
[16]	Li Y, Xin Y, Chai L, et al. Microstructures and shape memory characteristics of dual-phase Co–Ni–Ga high-temperature shape memory alloys. Acta Mater, 2010, 58(10): 3655 doi: 10.1016/j.actamat.2010.03.001
[17]	Jiang H X, Yang S Y, Wang C P, et al. Martensitic transformation and shape memory effects in Co?V?Al alloys at high temperatures. J Alloys Compd, 2019, 786: 648 doi: 10.1016/j.jallcom.2019.01.216
[18]	S?derberg O, Aaltio I, Ge Y, et al. Ni?Mn?Ga multifunctional compounds. Mater Sci Eng A, 2008, 481-482: 80 doi: 10.1016/j.msea.2006.12.191
[19]	Karaca H E, Karaman I, Basaran B, et al. Magnetic field and stress induced martensite reorientation in NiMnGa ferromagnetic shape memory alloy single crystals. Acta Mater, 2006, 54(1): 233 doi: 10.1016/j.actamat.2005.09.004
[20]	Ma Y Q, Jiang C B, Li Y, et al. Study of Ni_50+xMn₂₅Ga_25?x (x=2?11) as high-temperature shape-memory alloys. Acta Mater, 2007, 55(5): 1533 doi: 10.1016/j.actamat.2006.10.014
[21]	Xu H B, Ma Y Q, Jiang C B. A high-temperature shape-memory alloy Ni₅₄Mn₂₅Ga₂₁. Appl Phys Lett, 2003, 82(19): 3206 doi: 10.1063/1.1572540
[22]	Chernenko V A, Villa E, Besseghini S, et al. Giant two-way shape memory effect in high-temperature Ni?Mn?Ga single crystal. Phys Procedia, 2010, 10: 94 doi: 10.1016/j.phpro.2010.11.081
[23]	Chernenko V A, L’vov V, Pons J, et al. Superelasticity in high-temperature Ni?Mn?Ga alloys. J Appl Phys, 2003, 93(5): 2394 doi: 10.1063/1.1539532
[24]	Ma Y Q, Jiang C B, Feng G, et al. Thermal stability of the Ni₅₄Mn₂₅Ga₂₁ Heusler alloy with high temperature transformation. Scr Mater, 2003, 48(4): 365 doi: 10.1016/S1359-6462(02)00450-5
[25]	Li Y, Xin Y, Jiang C B, et al. Shape memory effect of grain refined Ni₅₄Mn₂₅Ga₂₁ alloy with high transformation temperature. Scr Mater, 2004, 51(9): 849 doi: 10.1016/j.scriptamat.2004.07.010
[26]	辛燕, 柴亮. Fe對Ni?Mn?Ga形狀記憶合金相變和力學性能的影響. 北京科技大學學報, 2013, 35(8):1027 Xin Y, Chai L. Effect of Fe addition on the martensitic transformation behavior and mechanical properties of Ni?Mn?Ga shape memory alloys. J Univ Sci Technol Beijing, 2013, 35(8): 1027
[27]	Ma Y Q, Yang S Y, Liu Y, et al. The ductility and shape-memory properties of Ni?Mn?Co?Ga high-temperature shape-memory alloys. Acta Mater, 2009, 57(11): 3232 doi: 10.1016/j.actamat.2009.03.025
[28]	Ma Y Q, Lai S L, Yang S Y, et al. Ni₅₆Mn_25-xCr_xGa₁₉ (x=0, 2, 4, 6) high temperature shape memory alloys. Trans Nonferrous Met Soc China, 2011, 21(1): 96 doi: 10.1016/S1003-6326(11)60683-3
[29]	Xin Y, Zhou Y. Martensitic transformation and mechanical properties of NiMnGaV high-temperature shape memory alloys. Intermetallics, 2016, 73: 50 doi: 10.1016/j.intermet.2016.03.005
[30]	Ma Y Q, Yang S Y, Jin W J, et al. Ni₅₆Mn_25?xCu_xGa₁₉ (x=0, 1, 2, 4, 8) high-temperature shape-memory alloys. J Alloys Compd, 2009, 471(1-2): 570 doi: 10.1016/j.jallcom.2008.07.016
[31]	Zhang X, Liu Q S. A dual-phase Ni?Mn?Ga?Gd high-temperature shape memory alloy with large shape recovery ratio. Rare Met Mater Eng, 2017, 46(9): 2375 doi: 10.1016/S1875-5372(17)30200-X
[32]	董桂馥, 李學慧, 李艷琴, 等. Ti含量對Ni₅₃Mn_23.5Ga_23.5-xTi_x鐵磁性形狀記憶合金組織和性能的影響. 稀有金屬材料與工程, 2010, 39(10):1785 Dong G F, Li X H, Li Y Q, et al. Effect of the Ti content on microstructure and properties of Ni₅₃Mn_23.5Ga_23.5-xTi_x ferromagnetic shape memory alloy. Rare Met Mater Eng, 2010, 39(10): 1785
[33]	Dong G F, Cai W, Gao Z Y. Microstructure and martensitic transformation of Ni?Mn?Ga?Ti ferromagnetic shape memory alloys. J Alloys Compd, 2008, 465(1-2): 173 doi: 10.1016/j.jallcom.2007.10.138
[34]	Dong G F, Gao Z Y, Tan C L, et al. Phase transformation and magnetic properties of Ni?Mn?Ga?Ti ferromagnetic shape memory alloys. J Alloys Compd, 2010, 508(1): 47 doi: 10.1016/j.jallcom.2010.04.157
[35]	白靜, 楊禛, 趙晨羽, 等. NiMnGaTi鐵磁形狀記憶合金的馬氏體相變和磁性能. 東北大學學報(自然科學版), 2019, 40(10):1398 Bai J, Yang Z, Zhao C Y, et al. Martensitic transformation and magnetic properties of NiMnGaTi ferromagnetic shape memory alloy. J Northeast Univ (Nat Sci), 2019, 40(10): 1398
[36]	王磊. NiMnGa基形狀記憶合金的顯微組織研究[學位論文]. 北京: 華北電力大學(北京), 2018 Wang L. Research on Microstructure of NiMnGa-Based Shape Memory Alloys [Dissertation]. Beijing: North China Electric Power University, 2018
[37]	Zhang X, Sui J H, Yang Z Y, et al. Thermal stability of Ni₅₄Mn₂₅Ga_20.9Gd_0.1 high-temperature shape memory alloy with large reversible strain. Mater Lett, 2014, 123: 250 doi: 10.1016/j.matlet.2014.02.088
[38]	賈皓東, 周張健. 高強度耐腐蝕ODS?FeCrAl 合金微觀結構、力學性能研究進展. 工程科學學報. DOI: 10.13374/j.issn2095-9389.2020.12.17.005 Jia H D, Zhou Z J. Research progress in microstructure and service performance of high-strength and corrosion-resistant ODS−FeCrAl alloy, Chin J Eng. DOI: 10.13374/j.issn2095-9389.2020.12.17.005