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Volume 43 Issue 5
May  2021
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Article Contents
FENG Li-li, CHEN Yue, LI Ji-gang, TANG Si-yao, DU Jun-zhao, LI Tong-yan, LI Xing-guo. Research progress in carbon-based composite molded bipolar plates[J]. Chinese Journal of Engineering, 2021, 43(5): 585-593. doi: 10.13374/j.issn2095-9389.2021.01.02.001
Citation: FENG Li-li, CHEN Yue, LI Ji-gang, TANG Si-yao, DU Jun-zhao, LI Tong-yan, LI Xing-guo. Research progress in carbon-based composite molded bipolar plates[J]. Chinese Journal of Engineering, 2021, 43(5): 585-593. doi: 10.13374/j.issn2095-9389.2021.01.02.001

Research progress in carbon-based composite molded bipolar plates

doi: 10.13374/j.issn2095-9389.2021.01.02.001
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  • Corresponding author: E-mail: sharpfl@buaa.edu.cn
  • Received Date: 2021-01-02
  • Publish Date: 2021-05-25
  • Bipolar plates are significant components in proton exchange membrane fuel cells (PEMFCs), thus playing a decisive role in the weight, volume, efficiency, durability, and cost of battery stacks. At present, the preparation technologies of metal and graphite plate stacks have become relatively mature, and have been widely used in the fields of commercial and passenger vehicles. However, production of composite material bipolar plates has not been marketed on a large scale in China due to the incomplete localization of raw material formulation, absence of mass production lines and high production cost. Therefore, it is of great significance to find low-cost raw materials, screen raw material compositions and ratios, optimize processing conditions including molding temperature, pressure and time, and shorten the processing cycle for the industrialization of composite bipolar plates. In this review, the characteristics of metal bipolar plates, graphite bipolar plates and composite material bipolar plates were compared. Moreover, the molding process and its advantages in composite bipolar plate production were introduced. Subsequently, recent progress in research of carbon-based composite molded bipolar plates was summarized. This includes resin/graphite composite bipolar plates using thermosetting resins such as phenol formaldehyde resin, epoxy resin and vinyl ester resin as the binder, and carbon black, carbon fiber and carbon nanotube reinforced composite bipolar plates. The effects of the types and ratios of raw materials and molding process conditions on the performance of bipolar plates were emphasized. Finally, the industrialization status of composite bipolar plates was discussed, and the problems faced by major composite bipolar plate manufacturers at home and abroad were pointed out. Prospects in the development of composite bipolar plates were also explored. Additionally, unified performance test standards for composite bipolar plates were recommended to make the performance of products developed by different enterprises comparable.

     

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  • [1]
    李偉, 李爭顯, 劉林濤, 等. 質子交換膜燃料電池金屬雙極板表面改性研究進展. 表面技術, 2018, 47(10):81

    Li W, Li Z X, Liu L T, et al. Research progress on surface modification of metal bipolar plate for proton exchange membrane fuel cell. Surf Technol, 2018, 47(10): 81
    [2]
    安富強, 趙洪量, 程志, 等. 純電動車用鋰離子電池發展現狀與研究進展. 工程科學學報, 2019, 41(1):22

    An F Q, Zhao H L, Cheng Z, et al. Development status and research progress of power battery for pure electric vehicles. Chin J Eng, 2019, 41(1): 22
    [3]
    鐘雪虎, 陳玲玲, 韓俊偉, 等. 廢舊鋰離子電池資源現狀及回收利用. 工程科學學報, 2021, 43(2):161

    Zhong X H, Chen L L, Han J W, et al. Overview of present situation and technologies for the recovery of spent lithium-ion batteries. Chin J Eng, 2021, 43(2): 161
    [4]
    鮑德佑. 質子交換膜燃料電池的研究開發進展. 高科技與產業化, 1994(增刊1): 4

    Bao D Y. Research progress of proton exchange membrane fuel cell. High Technol Industuialigation, 1994(Sup1): 4
    [5]
    Wang Y, Yuan H, Martinez A, et al. Polymer electrolyte membrane fuel cell and hydrogen station networks for automobiles: Status, technology, and perspectives. Adv Appl Energy, 2021, 2: 100011 doi: 10.1016/j.adapen.2021.100011
    [6]
    王曉佳, 陳咪. 基于線性回歸分析的新能源汽車與傳統汽車能耗與使用成本比較研究//第十三屆(2018)中國管理學年會. 杭州, 2018: 442

    Wang X J, Chen M. Comparison of energy consumption and usage cost between new energy vehicles and traditional vehicles based on linear regression analysis // The 13th (2018) China Management Academic Annual Conference. Hangzhou, 2018: 442
    [7]
    Samu A, Pertti K, Jari I, et al. Bipolar Plate, Method for Producing Bipolar Plate and PEM Fuel Cell: United State Patent, EP20090142645.2009-6-4
    [8]
    韓月桐, 張鵬超, 史杰夫, 等. 質子交換膜燃料電池中TA1雙極板的表面改性研究. 中國腐蝕與防護學報, 2021, 41(1):125

    Han Y T, Zhang P C, Shi J F, et al. Surface modification of TA1 bipolar plate for proton exchange membrane fuel cell. J Chin Soc Corros Prot, 2021, 41(1): 125
    [9]
    Song Y, Zhang C, Ling C Y, et al. Review on current research of materials, fabrication and application for bipolar plate in proton exchange membrane fuel cell. Int J Hydrog Energy, 2020, 45(54): 29832 doi: 10.1016/j.ijhydene.2019.07.231
    [10]
    Hermann A, Chaudhuri T, Spagnol P. Bipolar plates for PEM fuel cells: A review. Int J Hydrog Energy, 2005, 30(12): 1297 doi: 10.1016/j.ijhydene.2005.04.016
    [11]
    Renata W. Carbon-based materials for bipolar plates for low-temperatures PEM fuel cells? ?A review. Funct Mater Lett, 2019, 12(2): 1930001 doi: 10.1142/S1793604719300019
    [12]
    樊潤林, 彭宇航, 田豪, 等. 燃料電池復合石墨雙極板基材的研究進展: 材料、結構與性能. 物理化學學報, https://doi.org/10.3866/PKU.WHXB202009095.

    Fan R L, Peng Y H, Tian H, et al. Graphite-filled composite bipolar plates for fuel cells: material, structure, and performance. Acta Phys-Chim Sin, https://doi.org/10.3866/PKU.WHXB202009095.
    [13]
    Kamarudin S K, Daud W R W, Md Som A, et al. Technical design and economic evaluation of a PEM fuel cell system. J Power Sources, 2006, 157(2): 641 doi: 10.1016/j.jpowsour.2005.10.053
    [14]
    康啟平, 張國強, 劉艷秋, 等. 質子交換膜燃料電池復合材料雙極板研究進展. 中北大學學報(自然科學版), 2019, 40(5):414

    Kang Q P, Zhang G Q, Liu Y Q, et al. Research progress of composite bipolar plates for proton exchange membrane fuel cells. J North Univ China Nat Sci Ed, 2019, 40(5): 414
    [15]
    趙秋萍, 牟志星, 張斌, 等. 質子交換膜燃料電池雙極板材料研究進展. 化工新型材料, 2019, 47(11):52

    Zhao Q P, Mu Z X, Zhang B, et al. Research progress of bipolar plate material for proton exchange membrane fuel cell. New Chem Mater, 2019, 47(11): 52
    [16]
    Kang K, Park S, Ju H. Effects of type of graphite conductive filler on the performance of a composite bipolar plate for fuel cells. Solid State Ionics, 2014, 262: 332 doi: 10.1016/j.ssi.2013.11.024
    [17]
    冀曉燕, 李愛菊, 王威強, 等. 樹脂/石墨PEMFC雙極板的制備工藝與性能研究綜述. 材料導報, 2013, 27(17):87 doi: 10.3969/j.issn.1005-023X.2013.17.018

    Ji X Y, Li A J, Wang W Q, et al. Review of study on preparation and performance of resin/graphite PEMFC bipolar plates. Mater Rev, 2013, 27(17): 87 doi: 10.3969/j.issn.1005-023X.2013.17.018
    [18]
    Zhang S W, Wan Z P, Shen Y Q, et al. Fabrication of graphite composite bipolar plate for miniature PEMFCs by micro planing with multi-cutter. Key Eng Mater, 2013, 589-590: 617 doi: 10.4028/www.scientific.net/KEM.589-590.617
    [19]
    Kakati B K, Sathiyamoorthy D, Verma A. Electrochemical and mechanical behavior of carbon composite bipolar plate for fuel cell. Int J Hydrog Energy, 2010, 35(9): 4185 doi: 10.1016/j.ijhydene.2010.02.033
    [20]
    Minke C, Hickmann T, dos Santos A R, et al. Cost and performance prospects for composite bipolar plates in fuel cells and redox flow batteries. J Power Sources, 2016, 305: 182 doi: 10.1016/j.jpowsour.2015.11.052
    [21]
    胡斌, 項林憶, 何光建. 質子交換膜燃料電池用聚合物/導電填料復合材料雙極板的研究進展. 塑料工業, 2020, 48(增刊1): 26

    Hu B, Xiang L Y, He G J. Research progress in PEMFC polymer/conductive filler composite material bipolar plates. China Plast Ind, 2020, 48(Sup1): 26
    [22]
    Cunningham B D, Huang J, Baird D G. Review of materials and processing methods used in the production of bipolar plates for fuel cells. Int Mater Rev, 2007, 52(1): 1 doi: 10.1179/174328006X102556
    [23]
    李曉燕, 任圓, 甘文君. 熱固性樹脂的增韌進展. 熱固性樹脂, 2010, 25(5):41

    Li X Y, Ren Y, Gan W J. Progress in toughening thermosetting resins. Thermosetting Resin, 2010, 25(5): 41
    [24]
    陳杰, 馬春柳, 劉邦, 等. 熱固性樹脂及其固化劑的研究進展. 塑料科技, 2019, 47(2):95

    Chen J, Ma C L, Liu B, et al. Research progress of thermosetting resins and their curing agents. Plast Sci Technol, 2019, 47(2): 95
    [25]
    Simaafrookhteh S, Khorshidian M, Momenifar M. Fabrication of multi-filler thermoset-based composite bipolar plates for PEMFCs applications: Molding defects and properties characterizations. Int J Hydrog Energy, 2020, 45(27): 14119 doi: 10.1016/j.ijhydene.2020.03.105
    [26]
    Yao K, Adams D, Hao A, et al. Highly conductive and strong graphite-phenolic resin composite for bipolar plate applications. Energy Fuels, 2017, 31(12): 14320 doi: 10.1021/acs.energyfuels.7b02678
    [27]
    陰強, 李愛菊, 孫康寧, 等. 酚醛樹脂/石墨雙極板復合材料的實驗研究. 人工晶體學報, 2007, 36(4):807 doi: 10.3969/j.issn.1000-985X.2007.04.020

    Yin Q, Li A J, Sun K N, et al. Study of PF resin/graphite composite for bipolar plate. J Synth Cryst, 2007, 36(4): 807 doi: 10.3969/j.issn.1000-985X.2007.04.020
    [28]
    Jiang B Y, Stübler N, Wu W Q, et al. Manufacturing and characterization of bipolar fuel cell plate with textile reinforced polymer composites. Mater Des, 2015, 65: 1011 doi: 10.1016/j.matdes.2014.10.044
    [29]
    Kang S J, Kim D O, Lee J H, et al. Solvent-assisted graphite loading for highly conductive phenolic resin bipolar plates for proton exchange membrane fuel cells. J Power Sources, 2010, 195(12): 3794 doi: 10.1016/j.jpowsour.2009.11.064
    [30]
    Mathur R B, Dhakate S R, Gupta D K, et al. Effect of different carbon fillers on the properties of graphite composite bipolar plate. J Mater Process Technol, 2008, 203(1-3): 184 doi: 10.1016/j.jmatprotec.2007.10.044
    [31]
    Chen H, Liu H B, Yang L, et al. Effects of resin type on properties of graphite/polymer composite bipolar plate for proton exchange membrane fuel cell. J Mater Res, 2011, 26(23): 2974 doi: 10.1557/jmr.2011.358
    [32]
    羅曉寬. 質子交換膜燃料電池膨脹石墨雙極板研究[學位論文]. 大連: 大連理工大學, 2017

    Luo X K. Study on the Bipolar Plate of Expanded Graphite of Proton Exchange Membrance Fuel Cells [Dissertation]. Dalian: Dalian University of Technology, 2017
    [33]
    王成國, 吳宏, 郭少云. 乙烯基酯樹脂/石墨雙極板復合材料的制備. 高分子材料科學與工程, 2014, 30(8):125

    Wang C G, Wu H, Guo S Y. Preparation of vinyl ester resin/graphite composite for bipolar plate. Polym Mater Sci Eng, 2014, 30(8): 125
    [34]
    吳晴, 李建, 張鵬磊. 固化劑對乙烯基酯樹脂/碳纖維復合材料性能的影響. 湖北汽車工業學院學報, 2019, 33(4):68

    Wu Q, Li J, Zhang P L. Effect of curing agent content on properties of vinyl ester resin/carbon fiber composites. J Hubei Univ Automot Technol, 2019, 33(4): 68
    [35]
    Kim M, Choe J, Lim J W, et al. Manufacturing of the carbon/phenol composite bipolar plates for PEMFC with continuous hot rolling process. Compos Struct, 2015, 132: 1122 doi: 10.1016/j.compstruct.2015.07.038
    [36]
    Lee D, Lim J W, Lee D G. Cathode/anode integrated composite bipolar plate for high-temperature PEMFC. Compos Struct, 2017, 167: 144 doi: 10.1016/j.compstruct.2017.01.080
    [37]
    Lee H, Han K. Effect of surface-modified carbon fiber on the mechanical properties of carbon/epoxy composite for bipolar plate of PEMFC. Transctions Korean Hydrog New Energy Soc, 2020, 31(1): 49 doi: 10.7316/KHNES.2020.31.1.49
    [38]
    張修平. 乙烯基酯樹脂/改性碳纖維復合材料制備及性能研究[學位論文]. 長春: 長春工業大學, 2016

    Zhang X P. Preparation and Study of Vinyl Ester Resin/ Modified Carbon Fiber Composites [Dissertation]. Changchun: Changchun University of Technology, 2016
    [39]
    Yu H N, Lim J W, Suh J D, et al. A graphite-coated carbon fiber epoxy composite bipolar plate for polymer electrolyte membrane fuel cell. J Power Sources, 2011, 196(23): 9868 doi: 10.1016/j.jpowsour.2011.06.102
    [40]
    Antunes R A, de Oliveira M C L, Ett G, et al. Carbon materials in composite bipolar plates for polymer electrolyte membrane fuel cells: A review of the main challenges to improve electrical performance. J Power Sources, 2011, 196(6): 2945 doi: 10.1016/j.jpowsour.2010.12.041
    [41]
    劉家好, 吳赟, 呂海洋, 等. 炭黑填充型導電高分子材料的研究進展. 廣州化工, 2020, 48(9):19

    Liu J H, Wu Y, Lü H Y, et al. Research progress on conductive polymer filled with carbon black. Guangzhou Chem Ind, 2020, 48(9): 19
    [42]
    Lim J W. Development of carbon composite bipolar plates for PEMFC. Compos Res, 2019, 32(5): 222
    [43]
    Gautam R K, Kar K K. Synergistic effects of carbon fillers of phenolic resin based composite bipolar plates on the performance of PEM fuel cell. Fuel Cells, 2016, 16(2): 179 doi: 10.1002/fuce.201500051
    [44]
    陰強. 碳納米管增強酚醛樹脂/石墨雙極板復合材料的制備與性能研究[學位論文]. 濟南: 山東大學, 2008

    Yin Q. Fabrication and Properties of Carbon Nanotubes Reinforced Phenol Formaldehyde Resin/Graphite Composite for Bipolar Plate [Dissertation]. Jinan: Shandong University, 2008
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