The control of oxygen content and composition and the transformation conditions of non-metallic inclusions in gear steel are calculated with the thermodynamic calculation software Factsage. The results show that the composition of non-metallic inclusions with high plasticity in 20CrMoH steel is as follows (mass fraction):SiO
2 0% to 10%,Al
2O
3 22% to 55%,CaO 42% to 60%,and MgO 5% to 10%. Under this condition,the mass fraction of aluminum in molten steel is above 0.020%,that of calcium is above 0.7×10
-6,and the activity of oxygen in molten steel is about 0.000 5%. If the compositions of refining slag with CaO > 40%, Al
2O
3 ≤ 37%, MgO 10%, (% CaO +% MgO)/% SiO
2=10,and the SiO
2 content as low as possible are selected,Al
2O
3 and MgO·Al
2O
3 in molten steel can transform into calcium aluminates with low melting point. It is found that the contents of T[O]at the end of LF and RH refining both decrease with the increase in slag basicity,and the content of T[O]decreases with increasing the content of Al
2O
3 in the slag. In the refining process,the composition of the non-metallic inclusions changes in order of "inclusions of the Al
2O
3 system→inclusions of the MgO-Al
2O
3 system→inclusions of the CaO-MgO-Al
2O
3 system",among which the change of inclusions of the MgO-Al
2O
3 system to inclusions of the CaO-MgO-Al
2O
3 system is inwardly from the outside surface and the reaction speed is relatively slower. Thus,at the end of the ladle furnace refining (LF),there are still many unchanged MgO-Al
2O
3 system inclusions. The T[O]content of the steel significantly affects the composition change of the inclusions and decreasing T[O]content favors the change of inclusions.