The liquid steel was refined in the laboratory and in converter steel shop with the mixture of CaO-Al
2O
3 and Cao-Al
2O
3-CaC
2. The influence of the mixture added amount on the desulfurization and total oxygen of steel has been investigated. Refinin of steel with the mixture of Cao-Al
2O
3, the desulfurization of 20%~40% was reached; Refining of steel with the mixture of CaO-Al
2O
3-CaC
2, the desulfurization of 40% was reached, and the total oxygen in the steel was reduced under 5×10
-5.