In accordance with the coexistence theory of metallic melts structure involving compound formation and Fe-Al phase diagram as well, and by means of regression analysis, the structral units of Fe-Al melt at 1 315℃ and 1 600℃ have been determined. On the basis of these structural units, the calculating models of mass action concentrations have been deduced. The agreement between calculated values of
NFe,
NAl and measured
αFe,
αAl respectively is satisfactory.