Measurement and Calculation of ReCl<sub>3</sub>-LiCl (Re: La, Ce) Phase Diagrams

Qiao Zhiyu; Wang Mingsheng; Zheng Chaogui; Duan Shuzhen

doi:10.13374/j.issn1001-053x.1989.06.034

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Qiao Zhiyu, Wang Mingsheng, Zheng Chaogui, Duan Shuzhen. Measurement and Calculation of ReCl3-LiCl (Re: La, Ce) Phase Diagrams[J]. Chinese Journal of Engineering, 1989, 11(6): 598-603. doi: 10.13374/j.issn1001-053x.1989.06.034

Citation:

Qiao Zhiyu, Wang Mingsheng, Zheng Chaogui, Duan Shuzhen. Measurement and Calculation of ReCl₃-LiCl (Re: La, Ce) Phase Diagrams[J]. Chinese Journal of Engineering, 1989, 11(6): 598-603. doi: 10.13374/j.issn1001-053x.1989.06.034

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Measurement and Calculation of ReCl₃-LiCl (Re: La, Ce) Phase Diagrams

doi: 10.13374/j.issn1001-053x.1989.06.034

1. Dept. of Physical Chemistry;
2. Dept. of Chemistry, Peking University

Funds:

The Proiect Supported by National Natural Science Fundation of China

Received Date: 1989-04-06
Available Online: 2021-11-15

Abstract

Abstract

In this paper the phase diagrams of LaCl₃-LiCl and CeCl₃-LiCl systems have been experimentally determined and theoretically calculated. Bath are simple eutectic systems. The eutectic points are at 25mol% LaCl₃, 508℃ and 27mol% CeCl₃, 494℃, respectively. The optimized phase diagrams and thermodynamical data of LaCl₃-LiCl and CeCl₃-LiCl systems with self consistency are a better basis for constructing ternary phase diagrams.
- phase diagram,
- measurement and calculation,
- rare earth element,
- ReCl₃-LiCl