Multifunctional water-based surface tolerant coating and its protective performance
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摘要: 基于銹蝕碳鋼表面,針對一種多功能型的酸性水性低表面處理涂料中主要防銹組分和配制工藝對涂料和涂層性能的影響進行研究,考察涂層的防護性能,并與同類進口涂層進行對比.結果表明:在基材表面處理等級為St1時,涂層附著力隨著防銹組分含量的增加均呈現先上升再下降的趨勢,螯合劑所含活性基團穩定了基材表面銹蝕,帶來涂層附著性能的提高.復合銹轉化劑將基材表面銹蝕絡合轉化,進一步提高涂層附著力.最佳配制工藝為后加復合銹轉化劑與低速攪拌相結合.所得涂層在基材表面處理等級分別為St1和St3時附著性能無明顯差異,附著力達5 MPa.涂層耐蝕性能也無明顯差異:耐鹽水1200 h,耐鹽霧1000 h,耐紫外老化2000 h,遠高于進口同類水性帶銹底漆,適合應用于大氣環境中復雜鋼鐵構件的維護.Abstract: Based on carbon steel surface corrosion,a study was conducted on multifunction acid water-based surface tolerant coatings. The focus was placed on the effect of antirust components and preparation processes on the coating properties. The barrier property was evaluated and compared with imported counterparts. The results show that when the treatment level of the substrate material surface is St1,the adhesive force of the coatings rises at the beginning and then goes downward as the content of the antirust components keeps increasing. The chelating agent contains active groups which stabilize the substrate surface corrosion,resulting in the adhesion performance of the coatings increasing. The compound rust conversion agent improves the coating adhesive force further by translating the corroded substrate surface complexation. The best preparation process needs to mix at low speed and add the compound rust agent at the end of the steps. The adhesive forces of the coatings on the substrate material surfaces treated at St1 and St3 levels show no difference,and they are larger than 5 MPa. The corrosion resisting properties,resistant to salt water for 1200 h,salt spray for1000 h and ultraviolet aging for 2000 h,are much higher than those of similar imported water-based rust primers. The coatings are suitable for the maintenance of complex steel components in atmospheric environment.
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Key words:
- coatings /
- surface tolerance /
- chelating agents /
- adhesive force /
- corrosion resistance
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