Effect of niobium on second phase precipitation and austenite grain growth behavior in high-grade pipeline steel
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摘要: 基于雙亞點陣模型,計算了兩種不同鈮含量的高鋼級管線鋼在不同溫度下Nb、Ti和Al的析出量,測定了不同加熱溫度和保溫時間下奧氏體晶粒尺寸,建立兩種鋼奧氏體晶粒長大模型.發現Nb含量增加提高了其全固溶溫度,并且溫降過程中Nb析出量顯著增多,在晶界兩邊析出的細小碳氮化物對奧氏體晶粒長大有顯著的陰礙作用.高鈮鋼加熱溫度為1250℃時奧氏體晶粒顯著粗化,預測模型也不同于1050~1200℃的模型,但相同保溫溫度下晶粒尺寸明顯小于低鈮實驗鋼.通過數據擬合計算出高鈮鋼的長大激活能遠遠高于低鈮鋼,再次證明高Nb的管線鋼在1200℃以下能夠有效地細化奧氏體晶粒,預測模型與實驗值吻合較好.Abstract: Based on the double-sublattice model,the mass fractions of Nb,Ti and Al precipitates in two high-grade pipeline steels were calculated at different temperatures.The sizes of austenite grains in the two steels were determined at different heating temperatures after different soaking time.Two models were built to describe the austenite grain growth.It is found that the complete-solution temperature increases with the addition of Nb.The amount of small carbonitrides at the sides of grain boundaries,which hinder the austenite grain growth,also increases due to the drop of temperature.Austenite grains in the high-Nb steel remarkably coarsen when the soaking temperature is 1250℃,the prediction model is different from those used between 1050 and 1200℃,but the austenite grain size is obviously smaller than that of the low-Nb steel at the same soaking temperature.Based on the data-fit method,the austenite-growth activation energy of the high-Nb steel is calculated,which is much larger than that of the low-Nb steel.It is again proved that austenite grains are greatly refined in the high-Nb pipeline steel soaked at temperatures no more than 1200℃.The prediction models show good agreement with experimental data.
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Key words:
- pipeline steel /
- precipitation /
- grain growth /
- austenite /
- carbonitrides /
- kinetics
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