Theory analysis and experimental study on the removal of titanium from hot metal
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摘要: 通過對鐵水噴粉脫鈦熱力學和動力學的分析,建立了動力學模型,計算得到在1350℃不同停留時間條件下噴吹不同粒徑的脫鈦劑時,脫鈦、脫硅和脫碳量的變化情況.寶鋼魚雷罐噴吹富含氧化鐵的脫鈦劑,根據實際停留時間的計算值,分析得到其脫鈦劑的顆粒直徑在0.5~0.8 mm比較合適.通過感應爐實驗研究了脫鈦劑的脫鈦與脫硅規律,結果表明:脫鈦和脫硅基本同步進行,脫鈦率與脫硅率比在0.8~1左右,30 min內的脫硅率或脫鈦率在40%~80%之間.由此可見,噴吹高含量氧化鐵的粉劑脫鈦劑進行脫鈦是首選,可取得良好的脫鈦效果.Abstract: Based on the analysis of thermodynamics and kinetics of the titanium removal process from hot metal by the powders injection,a kinetic model was built to calculate the removal amounts of titanium,silicon,and carbon with the change in residence time in hot metal for different sizes of injected particles. With the help of the calculated actual residence time,it can be concluded that the particle size of titanium removal agents with a high content of iron oxide in the range of 0.5 to 0.8 mm is more suitable for titanium removal. The experiment in the induction furnace was performed to study the relationship between titanium removal and silicon removal of the titanium removal agents. The results show that titanium removal and silicon removal proceed synchronously,the related ratio of titanium removal amount to silicon removal amount is in the range of 0.8 to 1,and the removal efficiencies of titanium and silicon are both in 40%-80% after 30 min treatment. It is found that in the industrial practice,the particles injection with a high content of iron oxide as the titanium removal agent should be chosen firstly and the optimal effect can be attained.
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Key words:
- titanium removal /
- silicon removal /
- hot metal pretreatment /
- dynamics
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