Inclusion distribution in H13 ingots
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摘要: 對5.0 t H13鑄錠進行了解剖,采用掃描電鏡和能譜分析對鑄錠中夾雜物進行了形貌和組成分析,通過T[O]分析和金相顯微鏡統計分析對鑄錠中夾雜物的分布進行了研究.結果表明鑄錠中氧含量較高,平均值達到27.8×10-6,必須進一步精煉;鑄錠中夾雜物主要為近球形的CaO-Al2O3-SiO2夾雜,塊狀TiN-VN夾雜,沿晶界分布的條狀VC-CrC-MoC夾雜物和少量的CaS-MnS夾雜;尺寸較大的VC-CrC-MoC夾雜物對H13鋼的韌性影響較大,必須在后續熱處理及精煉中加以控制;T[O]和夾雜物在鑄錠中分布不均勻,在鑄錠頭部中心附近,夾雜物及總氧呈負偏聚;而在鑄錠中部及錠尾中心附近,夾雜物及總氧呈正偏聚;同時,鑄錠中下部大尺寸夾雜物數量比較高.為了表征夾雜物的偏聚程度,本文提出了夾雜物偏聚指數的新概念.在5 t H13鑄錠頭部中心夾雜物偏聚指數達到0.75~0.85,而在中下部夾雜物偏聚指數達到1.2~1.3.Abstract: Inclusions in a 5.0-t H13 ingot were studied by dissection. Morphologies and compositions of the inclusions were studied by scanning electron microscopy and energy dispersive spectrum,and the distribution of the inclusions was studied by T[O]analysis and metallographic microscopy. Results show that the average total oxygen in H13 ingot is high and reaches 27.8×10-6,so further refining is required. The inclusions in H13 are mainly near-spherical CaO-Al2O3-SiO2 inclusions,angular TiN-VN inclusions,large linear VC-CrC-MoC inclusions distributed in grain boundaries,and a few CaS-MnS inclusions. Large VC-CrC-MoC inclusions are harmful to the toughness of H13 steel,which should be controlled in following refining. The total oxygen and inclusions are uneven in ingots,the segregations of inclusions and total oxygen are negative around the core of the ingot head,while they are positive in the center and the lower part of the ingot; meanwhile,it is also found that the amount of larger inclusions in the center and the lower part of the ingot is higher. Inclusion segregation index is put forward to describe the segregation degree of inclusions,which is 0.75 to 0.85 around the core of the ingot head and 1.2 to 1.3 in the center and the lower part of the ingot.
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Key words:
- die steel /
- ingots /
- dissection /
- inclusions /
- segregation
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