Electrochemical corrosion performance of continuous columnar-grained BFe10-1-1 alloy
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摘要: 采用線性極化、電化學阻抗譜等電化學方法研究了連續柱狀晶組織BFe10-1-1合金在3.5%(質量分數)NaCl溶液中的耐蝕性能,并與普通鑄造多晶組織BFe10-1-1合金進行了對比.極化曲線測試結果表明,兩種合金具有相似的電化學行為,極化曲線都包括活性溶解區、活化-鈍化轉變區和極限電流區,但連續柱狀晶組織合金腐蝕速率小于普通鑄造多晶組織合金,主要是由于連續柱狀晶組織BFe10-1-1合金的微觀偏析程度較小,能有效避免枝晶間局部腐蝕的發生.電化學阻抗譜測試結果也表明,該合金的電荷傳遞電阻和腐蝕產物膜電阻均大于普通鑄造多晶組織合金,具有更高的耐蝕性.Abstract: The corrosion resistance of BFe10-1-1 alloy with continuous columnar-grained microstructure in a 3.5% NaCl solution was investigated by means of polarization tests and electrochemical impedance spectroscopy(EIS),and compared with that of BFe10-1-1 alloy with conventional polycrystalline microstructure fabricated by conventional casting.Polarization test results show that both BFe10-1-1 alloys have similar electrochemical behavior,and their polarization curves include three distinct regions,that is,the active dissolution region,the active-passive transition region and the limiting current region.However the corrosion rate of BFe10-1-1 alloy with continuous columnar-grained microstructure is lower than that of the one with conventional polycrystalline microstructure,as less microsegregation in BFe10-1-1 alloy with continuous columnar-grained microstructure can effectively avoid interdendritic corrosion.EIS spectra indicate that BFe10-1-1 alloy with continuous columnar-grained microstructure has a higher charge transfer resistance and a higher corrosion product film resistance compared with BFe10-1-1 alloy with conventional polycrystalline microstructure.The results further demonstrate that BFe10-1-1 alloy with continuous columnar-grained microstructure has a better corrosion resistance.
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Key words:
- copper-nickel alloys /
- directional solidification /
- microstructure /
- segregation /
- corrosion resistance
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