Comparative study on indoor and outdoor apparent aging properties of EPDM in the marine atmospheric environment
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摘要: 采用光澤度、掃描電鏡和傅里葉變換紅外分析技術等研究了三元乙丙橡膠(EPDM)在西沙大氣暴曬和室內加速老化試驗條件下的表觀形貌及結構的變化,探索了室內外老化表觀性能的相關性.結果表明:鹽霧試驗條件下光澤度基本沒有變化;熒光紫外試驗中光澤度在開始階段就快速下降,最后趨于平穩;在西沙大氣暴曬條件下,初始階段變化趨勢并不明顯,隨著老化時間的增加,光澤度值下降.紫外-鹽霧復合循環試驗條件下光澤度變化趨勢與西沙大氣條件下相似,說明西沙大氣暴曬試驗和紫外-鹽霧復合循環試驗具有很好的相關性,基于光澤度分析,紫外-鹽霧復合循環試驗的加速倍數是25~26.紅外光譜顯示在西沙大氣暴曬試驗和紫外-鹽霧復合試驗中可能有β-二酮的生成,鹽霧試驗條件下沒有β-二酮的生成.Abstract: Morphological and structural changes of ethylene-propylene-diene monomer(EPDM) in indoor-accelerated aging test and atmospheric exposure test were investigated by gloss meter,scanning electron microscopy(SEM) and Fourier transform infrared spectroscopy(FTIR).Correlation analysis was applied to discuss the outdoor and indoor apparent aging properties of EPDM.The results show that the gloss does not change in salt-fog test.In fluorescent UV test,the gloss decreases rapidly in the initial stage of aging and then reaches a plateau.The gloss changes inconspicuously in the initial stage of aging and then decreases with the aging time prolonging in atmospheric exposure test in the Xisha islands.The trend of gloss in indoor UV and salt-fog composite circulation experiment is similar to atmospheric exposure test in the Xisha islands.Atmospheric exposure test in the Xisha islands and indoor UV and salt-fog composite circulation experiment have a better correlation.Based on the analysis of gloss,the accelerated aging multiple of indoor UV and salt-fog composite circulation experiment is 25 to 26.FTIR spectra imply that β-diketone may form after EPDM is exposed to the artificial weathering environment produced by indoor UV and salt-fog composite circulation experiment and atmospheric exposure test in the Xisha islands.β-diketone is not formed in the salt-fog test condition.
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Key words:
- ethylene-propylene-diene monomer(EPDM) /
- aging /
- apparent properties /
- south China sea
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