Mechanism of carbon and oxygen reaction in RH decarburization of ultra low oxygen steel
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摘要: BOF+LF+RH+CC工藝路線生產IF鋼,在RH脫碳前,鋼水經脫氧和LF精煉后,鋼中自由氧達到極低水平.根據表觀脫碳速率常數的不同,這種極低氧鋼水的RH脫碳可以劃分為四個階段.與傳統三個階段的RH脫碳不同的是在低速脫碳階段和快速脫碳階段存在一個脫碳速率介于兩者之間的過渡階段.在正規溶液模型的基礎上,建立了能夠準確預報鋼液氧含量及頂渣FeO含量的RH脫碳模型.結果表明:在RH吹氧前,極低氧含量的鋼液與頂渣之間基本不傳氧;吹氧之后,鋼液氧含量呈線性增加,當鋼液氧勢大于頂渣氧勢后,鋼液向頂渣傳氧,渣中FeO含量上升;RH處理結束FeO含量較處理初始有所回升,但是仍處于極低水平,能夠有效降低頂渣對鋼液的二次氧化.Abstract: As for the IF steel making process of BOF+LF+RH+CC,the free oxygen content drops to a minimum level after deoxidization and LF refining,and right before RH decarburization.The RH decarburization reaction of steel with extreme low oxygen can be divided into four stages in terms of the apparent decarburization rate constant.Differed from traditional three-stage RH treatment,a transitional stage with medial decarburization occurs between the low and high decarburization stages.Based on the regular solution model,a decarburization model was developed to forecast oxygen content in the steel and FeO content in the top slag.It is found that there is no oxygen transferring between molten steel with extreme low oxygen and the top slag before RH blowing oxygen.After RH blowing oxygen,the oxygen content increases linearly,then oxygen transfers from the molten steel to the top slag which has a lower oxygen potential,and the FeO content increases consequently.Though the FeO content at the end of RH refining rises higher than the initial content,it is still fairly low enough to avoid reoxidation by the top slag to molten steel.
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Key words:
- low carbon steel /
- refining /
- decarburization /
- slags
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