Seawater temperature on the protection properties of epoxy coatings used in deep sea
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摘要: 采用電化學阻抗譜(EIS)技術,研究了環氧重防腐涂層在不同溫度海水中的腐蝕電化學行為.結果表明,隨著海水溫度的升高,涂層體系的涂層電容值的升高和涂層電阻值的降低均加快,說明海水溫度的升高,加速了涂層防護性能的下降,加快了基體金屬的腐蝕.浸泡初期,在不同溫度的海水中,水在涂層中的擴散均符合Fick擴散第二定律,擴散活化能為49.7kJ·mol-1.隨著海水溫度的升高,涂層中水的擴散系數增大,涂層吸水達到飽和的時間縮短,但飽和吸水量變化不大.Abstract: The electrochemical corrosion behavior of epoxy heavy-duty coatings immersed in seawater at different temperatures was investigated by electrochemical impedance spectroscopy (EIS). The results show that the increase in capacitance and the decrease in resistance of the coatings both change faster with rising temperature, indicating that higher seawater temperatures accelerate degradation of the coatings. At the initial immersed period, the diffusion process of seawater through the coatings follows the second Fick diffusion law at any seawater temperature and the diffusion activation energy is 49.7 kJ·mol-1. The diffusion coefficient of seawater across the coatings increases as the seawater temperature rises, and the time for the coatings to reach the maximum water absorption capacity shortens, but the saturated capacity for water absorption of the coatings changes little.
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Key words:
- seawater corrosion /
- epoxy resins /
- coatings /
- temperature /
- diffusion /
- electrochemical impedance spectroscopy (EIS)
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