Corrosion electrochemical behavior of electron beam welding joints of AF1410 steel
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摘要: 采用光學顯微鏡對AF1410電子束焊接接頭的組織結構進行了分析,并采用中性鹽霧腐蝕失重和電化學測試方法研究了焊縫熔合區和基體耐腐蝕性能及電化學行為.結果表明:電子束焊接后的焊縫位置為粗大回火馬氏體和析出碳化物;基體的腐蝕失重較焊縫熔合區低.電化學測試表明,焊縫熔合區的開路電位低于基體,腐蝕電流高于基材,阻抗值也較低,易腐蝕,這是回火馬氏體與析出的碳化物間存在電位差而導致的電化學反應,使材料在腐蝕介質中腐蝕失效.Abstract: Optical microscopy was used to analyze the microstructures of AF1410 steel welded joints after being electron beam welded.The corrosion resistant performance and the electrochemical behavior of the melting area and the base metal were also analyzed using the neutral salt spray corrosion weight loss and electrochemical testing methods.The results show that there are the thick tempered martensite and the precipitated carbides on the electron beam welding seam,and the corrosion weight of the base metal is less than that of the melting area.Electrochemical testing results indicate that the open circuit potential of the melting area is lower,the corrosion current is higher and the impedance is also lower than that of the base metal,and the melting area is more susceptible to corrosion.This is due to the electrochemical reaction driven by the potential difference between the tempered martensite and the carbide precipitation,which causes the corrosion failure of the material in the corrosion medium.
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