Effect of oxygen content on the formation behavior of sulfides in free-cutting steel
-
摘要: 通過實驗研究了氧含量對硫化物形態的影響.結果表明:隨著氧含量的增加,MnS夾雜物的形態由Ⅱ類向Ⅰ類轉變,其平均直徑和面積分數增大,數量減少,長寬比減小.通過數學模型以及Fe-Mn-S和Fe-Mn-S-O體系的四元相圖研究了氧含量對硫化物形態產生影響的機理.在氧質量分數高達0.022%時,凝固初期形成了大量的MnO系低熔點液態氧化物,促進了MnS的形成方式從共晶方式向偏晶方式轉變,形成Ⅰ類MnS;氧質量分數在0.01%以下時,凝固初期形成的MnO系低熔點液態氧化物較少,大部分MnS是在凝固末期以共晶形式析出,形成Ⅱ類MnS.Abstract: The effect of oxygen content on the morphology of sulfides was investigated by experiment. Experimental results show that the morphology of MnS inclusions changes from Type 11 to Type I with increasing oxygen content, the diameter and area fraction of MnS inclusions increase, but the number and mean aspect ratio of MnS inclusions decrease. The influence mechanism of oxygen content on the morphology of sulfides was studied on the basis of the mathematic model, the Fe-Mn-S ternary system diagram and the Fe-Mn-S-O quaternary system diagram. In the case of the oxygen mass fraction up to 0.022%, the liquid low-melting oxides rich with MnO were found at the early stage of solidification, these oxides made the formation behavior of MnS from eutectic reaction to monoteetic reaction, and Type I MnS formed. In the case of the low oxygen content less than about 0.01%, little liquid low-melting oxides rich with MnO were found at the early stage of solidification, most of MnS precipitated in an euteetie mode at final solidification, and Type Ⅱ MnS formed.
-
Key words:
- free-cutting steel /
- inclusions /
- manganese sulfide /
- morphology /
- phase diagrams
-

計量
- 文章訪問數: 307
- HTML全文瀏覽量: 122
- PDF下載量: 31
- 被引次數: 0