Texture and corrosion resistance in hot-dip galvanized steel sheet coatings
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摘要: 用X射線衍射和動電位掃描方法研究了熱浸鍍鋅鋼板鍍層織構、相分布和耐蝕性的關系.實驗結果表明,鍍鋅層中純鋅相的主要織構組分為{0002}基面織構,當鍍鋅層厚度增加時,純鋅相中{0002}基面織構密度水平增加,純鋅相自腐蝕電位升高、腐蝕電流密度減小以及耐蝕性增加.X射線衍射分析電化學剝離后的鐵鋅相,結果表明,鍍鋅層由純鋅相和合金相組成;電化學實驗表明,鍍鋅層各相耐蝕性不同,合金相的耐蝕性高于純鋅相的耐蝕性,且Fe-Zn合金相的耐蝕性隨鐵含量的增加而增加.Abstract: The relationships among textures,phase distribution and corrosion resistance of hot-dip galvanized coatings were investigated with X-ray diffraction and potentiodynamic techniques.Experimental results indicate the major texture component of pure zinc phase in the galvanized coatings is {0002} basal texture.As the thickness of the galvanized coatings increases,the {0002} basal texture component as well as the free corrosion potential increases,the corrosion current density decreases,and the corrosion resistance of the galvanized coatings increase.X-ray diffraction analysis results of an electrochemical stripping Fe-Zn phase coating show that the galvanized coatings are composed of alloy phases and pure zinc phase.Electrochemical experiments indicate the corrosion resistances of alloy phases and pure zinc phase are different,the corrosion resistance of alloy phases is higher than that of pure zinc phase,and the corrosion resistance of Fe-Zn alloy phase increases with the increase of iron content.
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Key words:
- hot-dip galvanizing /
- steel sheet /
- texture /
- phase distribution /
- corrosion resistance
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