CO2 corrosion behavior of 3Cr low-alloy pipeline steel and weld joints
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摘要: 采用高溫、高壓反應釜和電化學技術對3Cr低合金管線鋼及焊接接頭的CO2腐蝕行為進行研究.結果表明,3Cr低合金管線鋼在高溫、高壓CO2腐蝕環境中表面生成致密的富Cr腐蝕產物膜,這是其抗CO2腐蝕性能優于X65鋼的主要原因.3Cr低合金管線鋼焊接接頭中母材、熱影響區和焊縫的腐蝕產物膜特征相似,結構致密,均存在Cr元素的富集.與X65鋼相比,3Cr低合金管線鋼的自腐蝕電位較正,自腐蝕電流密度較低.在CO2腐蝕介質中,3Cr低合金管線鋼焊接接頭的母材區域作為陽極首先發生腐蝕,焊縫和熱影響區作為陰極受到保護.Abstract: The CO2 corrosion behavior of 3Cr low-alloy pipeline steel and its weld joints were researched with a high-pressure high-temperature autoclave and electrochemical techniques.The results showed that the corrosion product scales enriched Cr element were compact,which is the main reason that the CO2 corrosion resistance of 3Cr low-alloy pipeline steel is superior to that of X65 steel.The product scales of the base metal,heat affected zone (HAZ) and weld metal in 3Cr low alloy pipeline steel weld joints were similar with each other,with Cr enrichment and compact structure.Compared with X65 steel,the corrosion potential of 3Cr low alloy pipeline steel was more positive and the corrosion current density was lower.The base metal of 3Cr low alloy pipeline steel weld joints as an anode would be suffered corrosion firstly,and the weld metal and HAZ of the weld joints as cathodes would be protected.
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Key words:
- low-alloy steel /
- pipeline steel /
- weld joint /
- CO2 corrosion
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