Properties of sialon bonded corundum castables by in-situ nitridation sintering
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摘要: 以板狀剛玉為骨料,電熔白剛玉細粉、水合氧化鋁、Si粉和Al2O3微粉為基質,通過原位氮化反應制備了Sialon結合剛玉澆注料.研究了Sialon生成量對材料的常規物理性能、高溫強度和抗熱震性能的影響.用X射線衍射(XRD)和掃描電子顯微鏡(SEM)分析了材料的物相組成和顯微結構.結果表明:隨Sialon生成量的增加,成型所需加水量增加,Sialon結合剛玉澆注料的常溫抗折強度、體積密度下降,顯氣孔率略有增加,線變化率從微收縮到微膨脹;材料的高溫抗折強度和抗熱震性能明顯提高,熱震后的殘余強度保持率從不含Sialon的純剛玉澆注料的16%左右提高到50%左右.Abstract: Sialon-bonded corundum castables were prepared by in-situ nitridation sintering with tabular alumina as the aggregate,fused white corundum fine,hydratable alumina,Si powder and ultra-fine alumina as the matrix.The effects of sialon content on their physical properties,high-temperature strength and thermal shock resistance were investigated.The phase composition and microstructure of the samples were characterized by XRD and SEM.The results show that with increasing sialon content the water demand of the castables increases,the cold modulus of rupture and bulk density decrease,the apparent porosity slightly increases,and the permanent linear change varies from little shrinkage to little expansion.The hot modulus of rupture and thermal shock resistance of the castables obviously improve with increasing sialon content,and the residual strength ratio increases from 16% without sialon to 50%.
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Key words:
- sialon /
- corundum /
- castables /
- nitridation
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