Corrosion behavior and structure of oxide scales formed on hot rolled strips after coiling with different oxygen supplies
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摘要: 采用掃描電子顯微鏡(SEM)、X射線衍射儀、鹽霧實驗和電化學極化方法,研究了SS400熱軋帶鋼沿寬度方向不同位置氧化皮的組織、結構及其耐蝕性.結果表明,SS400邊部取樣位置的氧化皮厚度最厚且比較均勻,結構致密,存在明顯的Fe3O4/Fe共析組織.SS400邊部和板寬1/4處的成分主要為Fe3O4、Fe2O3和Fe,板寬中心位置的成分主要為Fe3O4和Fe.鹽霧腐蝕實驗表明,SS400邊部腐蝕最輕,板寬1/4處次之,板寬中心位置腐蝕最為嚴重.動電位極化曲線測試結果顯示,SS400邊部的腐蝕電位明顯高于其他兩個位置,腐蝕電流最小.熱軋帶鋼在卷曲后,由于帶鋼沿寬度方向不同位置的供氧差異,會導致氧化皮組織、結構的顯著不同,進而影響氧化皮的耐蝕性.Abstract: The structure of oxide scales and corrosion resistance of SS400 hot-rolled strips at different positions in plate width were studied by scanning electron microscopy (SEM), X-ray diffraction quantitative analysis, salt spray test and electrochemical methods. The results show that oxide scales at the plate edge are the thickest, relatively uniform and compact, and there is obvious magnetite/iron eutectoid in them. Oxide scales at the edge and one-fourth of plate width mainly consist of magnetite, hematite and magnetiteiron eutectoid, but oxide scales at the center are composed of magnetite and iron. It is shown by salt spray corrosion test that the corrosion rate is the minimum at the edge, the second at one-fourth of plate width, and the most serious at the center. By potentiodynamic polarization curve test, the corrosion potential at the edge is bigger than those at the two other parts, and the current is the minimum. After the hot rolled strips being coiled, the difference in oxygen supply in the width direction leads different structures of oxide scales, which influence the corrosion resistance of oxide scales.
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Key words:
- hot rolled strip /
- oxide scale /
- microstructure /
- corrosion behavior
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