Diffusion behavior of Cr element at the bonding interface of a 25Cr5MoA/Q235 solid-liquid cladding shaft
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摘要: 提出了金屬梯度結構軸的概念.研究了固-液復合的25Cr5MoA鋼/Q235鋼復合軸的組織、Cr元素的擴散以及結合界面附近顯微硬度的變化規律.結果表明:經過擠壓變形后,25Cr5MoA鋼/Q235鋼界面形成了良好的冶金結合,二者結合緊密,除了組織結構的差別外,二者的結合界面已經難以區分.結合界面附近Cr元素在固-液復合時得到充分擴散,并呈現出連續分布的形態.從界面向Q235鋼和25Cr5MoA鋼兩側±100μm范圍內,硬度呈現出均勻、連續分布.經過熱處理后,隨著加熱溫度的升高和加熱時間的延長,Cr元素在結合界面附近的分布更加均勻,分布曲線在界面的斜率進一步降低,使結合界面附近25Cr5MoA鋼的一側的顯微硬度大幅度降低,這有利于形成化學成分、組織以及性能的梯度變化.Abstract: The concept of metal gradient structure shafts was put forward firstly. The microstructure, diffusion behavior of Cr element, and variation in interracial microhardness of a 25CrSMoA/Q235 clad shaft prepared by solid-liquid cladding were investigated by scanning electron microscope and microhardness tester. The bonding interface of the 25CrSMoA/Q235 cladding shaft forms close metallurgical bonding after extrusion deformation, and it is difficult to be identified except the difference of individual structure. Cr element in a region adjacent to the bonding interface is fully diffusive and appears continuous distribution during solid-liquid bonding. Across a region ranging from the bonding interface to both sides by the distance of 100μm respectively, the microhardness distributes continuously and uniformly. Additionally, during heat treatment, increasing the heating temperature and holding time makes Cr distribution in a region adjacent to the bonding interface more uniform and the slope rate of Cr distribution curves at the bonding interface reduced more, which greatly reduce the microhardness at the 25CrSMoA side adjacent to the bonding interface. It is advantageous to form gradient variations in chemical composition, structure and mechanical properties at a region across the bonding interface.
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Key words:
- metal cladding /
- gradient structure /
- interface structure /
- element diffusion /
- bonding mechanism
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