Influence of Heat Treatment on the Coercivity and Morphology of the Magnet Powders Prepared by Mechanical Crushing Sintered NdFeB Magnets
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摘要: 將燒結NdFeB磁體進行機械破碎,得到粒徑大小運用于制備粘結磁體的磁粉,其矯頑力很低.在700~1050℃的溫度范圍內進行熱處理.實驗結果表明:適當地選取熱處理溫度,可以顯著地提高磁粉矯頑力,使其成為各向異性的高性能磁粉.用光學顯微鏡及SEM對熱處理前后磁粉的形態進行了觀察.未經熱處理的機械破碎磁粉,顆粒邊緣地區很細碎,并且有很多裂紋,中心區域則相當完整.熱處理后,磁粉的邊緣區域裂紋明顯減少并趨于平整,同時出現明顯的稀土及其氧化物的富集區.這表明,熱處理過程中磁粉可能發生了氧化,或者是將吸附的氧轉化成了稀土氧化物.Abstract: Heat treatment experiments were carried out to magnet powders prepared by crushing the sinteped NdFeB hard magnets, within the annealing temperature range from 700 to 1050℃. The results have shown tha the annealing treatment can effectively enhance the coercivity of the crushed powders, which is very low after the communtion, to relative high values. The microstructural changes of the magnet powders during the annealing were checked using optical and scanning electronic microscopes. It is found out that the magnet powders have many cracks in their surface layer caused by the mechanical crush, while their center parts remain free from crack. On the other side, the magnet powders after annealing treatment possess have few cracks in the surface layer. This change is considered as the result of the repairing effect of the annealing treatment to the damaged surface, which should be the reason for the enhanement of the coercivity of the magnet powders. Meanwhile, in the powders after annealing, more Nd-rich prticles can be observed evidently,some of which are determined as Nd-oxide. It indicates the ocurrence of oxidation is an other process happened during the annealing treatment,which should affect the recovery of the coercivity of the manget powders negatively.
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Key words:
- sintered NdFeB magnet /
- NdFeB magnet powders /
- coercivity /
- heat treatment
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